Aromatic interactions can greatly affect the stability and interactions of a crystal. They are the strongest such interactions after hydrogen bonding. , Recommanded Product: 2-Methyl-4,6-bis((octylthio)methyl)phenol, 110553-27-0, Name is 2-Methyl-4,6-bis((octylthio)methyl)phenol, molecular formula is C25H44OS2, belongs to thiazines compound. In a document, author is Rezki, Nadjet, introduce the new discover.
Alkylation of 5-(3-chlorobenzo[b]thien-2-yl)-1,2,4-triazole-3-thione with Epichlorhydrin and the Role of MW and Solid Support in the Reaction
An efficient eco-friendly approach has been adopted for the selective synthesis of 2,3-epoxypropylsulfanyltriazole 4 from the reaction of 1-chloro-2,3-epoxy-propane (2) with 5-(3-chlorobenzo[b]thien-2-yl)-4H-1,2,4-triazole-3-thione (1) under solvent free microwave conditions in the presence of a solid support. Instead, when the mixture of reactants was irradiated for prolonged time in the absence of solid support, triazolo[2,1-b]thiazine 3 was exclusively afforded in excellent yield. On the other hand, performing the irradiation in the presence of a base, mixtures of compounds 4 and 3 were obtained; the ratio of the two products was dependent on the nature of the base, although 4 was the major product in each case.
Recommanded Product: 2-Methyl-4,6-bis((octylthio)methyl)phenol, The result showed that such a combination of chemo- and biocatalysis improved the catalytic yield more than two times compared with that of sole metal catalysis.I hope my blog about 110553-27-0 is helpful to your research.
Reference:
Thiazine – an overview | ScienceDirect Topics,
,Thiazine | C4H5NS – PubChem