I found the field of Chemistry very interesting. Saw the article Electrochemical CO2 Reduction – The Effect of Chalcogenide Exchange in Ni-Isocyclam Complexes published in 2020.0. Product Details of 56-17-7, Reprint Addresses Ray, K (corresponding author), Humboldt Univ, Dept Chem, D-12489 Berlin, Germany.; Apfel, UP (corresponding author), Ruhr Univ Bochum, Dept Chem & Biochem, D-44801 Bochum, Germany.; Apfel, UP (corresponding author), Fraunhofer UMSICHT, D-46047 Oberhausen, Germany.. The CAS is 56-17-7. Through research, I have a further understanding and discovery of 2,2′-Disulfanediyldiethanamine dihydrochloride
Among the numerous homogeneous electrochemical CO2 reduction catalysts, [Ni(cyclam)](2+) is known as one of the most potent catalysts. Likewise, [Ni(isocyclam)](2+) was reported to enable electrochemical CO2 conversion but has received significantly less attention. However, for both catalysts, a purposeful substitution of a single nitrogen donor group by chalcogen atoms was never reported. In this work, we report a series of isocyclam-based Ni complexes with {ON3}, {SN3}, {SeN3}, and {N-4} moieties and investigated the influence of nitrogen/chalcogen substitution on electrochemical CO2 reduction. While [Ni(isocyclam)](2+) showed the highest selectivity toward CO2 reduction within this series with a Faradaic efficiency of 86% for the generation of CO at an overpotential of -1.20 V and acts as a homogeneous catalyst, the O- and S-containing Ni complexes revealed comparable catalytic activities at ca. 0.3 V milder overpotential but tend to form deposits on the electrode, acting as precursors for a heterogeneous catalysis. Moreover, the heterogeneous species generated from the O- and S-containing complexes enable a catalytic hydride transfer to acetonitrile, resulting in the generation of acetaldehyde. The incorporation of selenium, however, resulted in loss of CO2 reduction activity, mainly leading to hydrogen generation that is also catalyzed by a heterogeneous electrodeposit.
Product Details of 56-17-7. Welcome to talk about 56-17-7, If you have any questions, you can contact Gerschel, P; Battistella, B; Siegmund, D; Ray, K; Apfel, UP or send Email.
Reference:
Thiazine – an overview | ScienceDirect Topics,
,Thiazine | C4H5NS – PubChem