Computed Properties of C4H14Cl2N2S2. Recently I am researching about MACROCYCLIC LIGANDS; CARBON-DIOXIDE; COMPLEXES; ELECTROREDUCTION; KINETICS, Saw an article supported by the Fonds of the Chemical Industry (Liebig grant); Fonds of the Chemical Industry (Kekule fellowship); Deutsche Forschungsgemeinschaft (Emmy Noether grant)German Research Foundation (DFG) [AP242/2-1, AP242/5-1]; DFG (Cluster of Excellence Unifying Concepts in Catalysis)German Research Foundation (DFG) [EXC 314-2]; DFG (Heisenberg-Program)German Research Foundation (DFG); US DOE Office of ScienceUnited States Department of Energy (DOE) [DE-AC02-76SF00515]; US NIHUnited States Department of Health & Human ServicesNational Institutes of Health (NIH) – USA [P41-GM-103393, P30-EB-009998]; Fraunhofer Internal Programs [Attract 097-602175]; NATIONAL INSTITUTE OF BIOMEDICAL IMAGING AND BIOENGINEERINGUnited States Department of Health & Human ServicesNational Institutes of Health (NIH) – USANIH National Institute of Biomedical Imaging & Bioengineering (NIBIB) [P30EB009998] Funding Source: NIH RePORTER; NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCESUnited States Department of Health & Human ServicesNational Institutes of Health (NIH) – USANIH National Institute of General Medical Sciences (NIGMS) [P41GM103393] Funding Source: NIH RePORTER. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Gerschel, P; Warm, K; Farquhar, ER; Englert, U; Reback, ML; Siegmund, D; Ray, K; Apfel, UP. The CAS is 56-17-7. Through research, I have a further understanding and discovery of 2,2′-Disulfanediyldiethanamine dihydrochloride
The replacement of the opposing nitrogen atoms in 1,4,8,11-tetraazacyclotetradecane (cyclam) with two sulfur atoms in 1,8-dithia-4,11-diazacyclotetradecane (dithiacyclam) enables the electrochemical reduction of protons and CO(2)via the corresponding nickel(ii) complex at more positive potentials. In addition, a 10-fold enhancement in the proton reduction rate of [Ni(dithiacyclam)](2+) relative to [Ni(cylcam)](2+) was observed. The study provides vital insight into Nature’s choice of employing predominantly sulfur based ligand platforms in achieving biological proton and CO2 reductions.
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Reference:
Thiazine – an overview | ScienceDirect Topics,
,Thiazine | C4H5NS – PubChem