An article Synthesis of C- and N-Substituted 1,5,2,6-Dithiadiazocanes -Electrophilic-Nucleophilic Thioamination (ENTA) Reagents WOS:000651351800001 published article about S BOND FORMATION; H SULFENYLATION; SULFONAMIDES; SULFENOAMINATION; THIOMORPHOLINE; DERIVATIVES; SULFIDES; ACCESS; ION in [Javorskis, Tomas; Jurys, Arminas; Orentas, Edvinas] Vilnius Univ, Dept Organ Chem, Naugarduko 24, LT-03225 Vilnius, Lithuania; [Javorskis, Tomas; Bagdziunas, Gintautas] Ctr Phys Sci & Technol, Sauletekio Av 3, LT-10257 Vilnius, Lithuania; [Bagdziunas, Gintautas] Vilnius Univ, Life Sci Ctr, Inst Biochem, Sauletekio Av 7, LT-10257 Vilnius, Lithuania in 2021.0, Cited 38.0. Product Details of 56-17-7. The Name is 2,2′-Disulfanediyldiethanamine dihydrochloride. Through research, I have a further understanding and discovery of 56-17-7
A synthetic method is presented for S-N bond formation starting from cheap and affordable materials. We show that (un)substituted N-protected cyclic eight-membered C-2-symmetric sulfenamides have been prepared in a few steps using this procedure. The synthetic utility of these ambipolar derivatives was demonstrated in a variety of synthetic transformations affording different S,N-heterocyles of pharmaceutical relevance in one or two steps from simple starting materials.
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Reference:
Thiazine – an overview | ScienceDirect Topics,
,Thiazine | C4H5NS – PubChem