Application In Synthesis of 2,2′-Disulfanediyldiethanamine dihydrochloride. I found the field of Chemistry very interesting. Saw the article Sulfur substitution in a Ni(cyclam) derivative results in lower overpotential for CO2 reduction and enhanced proton reduction published in 2019.0, Reprint Addresses Apfel, UP (corresponding author), Ruhr Univ Bochum, Anorgan Chem 1, Univ Str 150, D-44801 Bochum, Germany.; Ray, K (corresponding author), Humboldt Univ, Inst Chem, Brook Taylor Str 2, D-12489 Berlin, Germany.; Apfel, UP (corresponding author), Fraunhofer UMSICHT, Osterfelder Str 3, D-46047 Oberhausen, Germany.. The CAS is 56-17-7. Through research, I have a further understanding and discovery of 2,2′-Disulfanediyldiethanamine dihydrochloride.
The replacement of the opposing nitrogen atoms in 1,4,8,11-tetraazacyclotetradecane (cyclam) with two sulfur atoms in 1,8-dithia-4,11-diazacyclotetradecane (dithiacyclam) enables the electrochemical reduction of protons and CO(2)via the corresponding nickel(ii) complex at more positive potentials. In addition, a 10-fold enhancement in the proton reduction rate of [Ni(dithiacyclam)](2+) relative to [Ni(cylcam)](2+) was observed. The study provides vital insight into Nature’s choice of employing predominantly sulfur based ligand platforms in achieving biological proton and CO2 reductions.
Application In Synthesis of 2,2′-Disulfanediyldiethanamine dihydrochloride. About 2,2′-Disulfanediyldiethanamine dihydrochloride, If you have any questions, you can contact Gerschel, P; Warm, K; Farquhar, ER; Englert, U; Reback, ML; Siegmund, D; Ray, K; Apfel, UP or concate me.
Reference:
Thiazine – an overview | ScienceDirect Topics,
,Thiazine | C4H5NS – PubChem