The transformation of simple hydrocarbons into more complex and valuable products has revolutionised modern synthetic chemistry. This type of reactivity has quickly become one of the cornerstones of modern catalysis. 5872-08-2, Name is (7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonic acid, formurla is C10H16O4S. In a document, author is Trinh, Trieu N., introducing its new discovery. Name: (7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonic acid.
A multicomponent access to 1,3-thiazine-6-phenylimino-5-carboxylates
The multicomponent reaction of ethyl 3-aminocrotonate (1), substituted phenylisothiocyanates (2a-i) and acetic anhydride (7), afforded facile access to a series of substituted 1,3-thiazine-6-phenylimino-5-carboxylates under mild conditions in 15-65% yields. Limited tolerance for modification of the anhydride moiety was noted with a significant reduction in yield for propionic and trifluoroacetic anhydrides. The use of benzoic anhydride favoured a two-component coupling product. (C) 2016 Elsevier Ltd. All rights reserved.
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Reference:
Thiazine – an overview | ScienceDirect Topics,
,Thiazine | C4H5NS – PubChem