Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner.10297-73-1, Name is 4′-(Methylsulfonyl)acetophenone, SMILES is C1=CC(=CC=C1[S](C)(=O)=O)C(C)=O, belongs to thiazines compound. However, they have proven to be challenging because of the mutual inactivation of both catalysts. In a document, author is Azotla-Cruz, Liliana, introduce the new discover, Safety of 4′-(Methylsulfonyl)acetophenone.
Crystal structure of methyl 1-allyl-4-methyl-1H-benzo[c][1,2]thiazine-3-carboxylate 2,2-dioxide
In the title compound, C14H15NO4S, the dihydrothiazine ring adopts a distorted sofa conformation with the S atom displaced from the mean plane through the N and C ring atoms by 0.767 (1) angstrom. The allyl substituent (C-C=C) is inclined to this mean plane by 78.5 (7)degrees and the acetate group [C(=O)-O-C] by 66.5 (3)degrees. In the crystal, molecules are linked by C-H center dot center dot center dot pi interactions forming chains propagating along the a-axis direction.
If you are interested in 10297-73-1, you can contact me at any time and look forward to more communication. Safety of 4′-(Methylsulfonyl)acetophenone.
Reference:
Thiazine – an overview | ScienceDirect Topics,
,Thiazine | C4H5NS – PubChem