Synthetic Route of 10297-73-1, In heterogeneous catalysis, catalysts provide a surface to which reactants bind in a process of adsorption. The reactant in an enzyme-catalyzed reaction is called a substrate.10297-73-1, Name is 4′-(Methylsulfonyl)acetophenone, SMILES is C1=CC(=CC=C1[S](C)(=O)=O)C(C)=O, belongs to thiazines compound. In a article, author is Zahedifar, Mahboobeh, introduce new discover of the category.
Unexpected Products from Mesoionic 1,3-Thiazinium and Oxazinium Olates: A Novel Access to 3,5-Diaryl-1,3-thiazine-2,4,6-trione and Alkoxy-3,5-diphenyl-3H-1,3-oxazine-2,6-dione Derivatives
The condensation of (chlorocarbonyl)ketenes 1 with N-phenylthiocarbamates 2 and N-phenylcarbamates 6 is postulated to lead to the formation of unstable mesoionic 1,3-thiazinium 4-olates I or 1,3-oxazinium 4-olates II, respectively. At room temperature, appropriately substituted mesoionic 1,3-thiazinium 4-olates I eliminated the corresponding alkene with generation of 3,5-diaryl-1,3-thiazine-2,4,6-trione derivatives 3. However, the methoxy-substituted compound 5 was stable at room temperature at least for several weeks. In the case of the mesoionic1,3-oxazinium 4-olates II an alkyl group migration affords 4-alkoxy-3,5-diphenyl-3H-1,3-oxazine-2,6-diones 7.
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Reference:
Thiazine – an overview | ScienceDirect Topics,
,Thiazine | C4H5NS – PubChem