3939-23-9, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.3939-23-9, Name is 3-Bromo-10H-phenothiazine, molecular formula is C12H8BrNS. In a Article, authors is Sailer, Markus£¬once mentioned of 3939-23-9
Synthesis and electronic properties of monodisperse oligophenothiazines
Starting from N-hexylphenothiazine, a versatile construction kit of brominated and borylated phenothiazines can be easily prepared by a sequence of bromination, bromo-lithium exchange/borylation, and Suzuki coupling. Subsequent Suzuki arylation of the building blocks gives soluble, monodisperse, and structurally well defined oligophenothiazines in good yields. The molecular weights at the peak maximum (Mp), obtained by GPC (gel permeation chromatography), and the actual molecular weights of the oligomer series, obtained by mass spectrometry, show excellent correlation. A QM/MM conformational analysis for the complete series reveals that the obvious butterfly-shaped phenothiazine structure multiplies and significantly reduces the hydrodynamic volume of the oligomers. The electronic properties (absorption and emission spectroscopy and cyclic voltammetry) give reasonable correlations with the chain length. With regard to the emission maxima, the effective conjugation length is already reached with the hexamer. Oligophenothiazines are highly fluorescent, with high fluorescence quantum yields, and are simultaneously highly electroactive, with low oxidation potentials.
A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 3939-23-9
Reference£º
Thiazine – an overview | ScienceDirect Topics,
Thiazine | C4H5NS – PubChem